In 1907, The Barcelona Museums Board creates the Special Library Committee. Two aspects should be mentioned about this period: on one hand the important efforts that Josep Puig i Cadafalch and Joaquim Folch i Torres made to consolidate the Library, and on the other the notable enrichment of the collection with the donation, in 1914, of the Vidal i Quadras Library, the Riquer acquisition in 1921, and the donation by Eduard Toda in 1931. In 1933, the Library moved to the Poble Espanyol, to premises created around the International Exhibition of 1929.

1931 Book-plate by Escornalbou, from the material in Eduard Toda's library, admitted to the Library this year

Eduard Toda donated two lots of old bindings from the 16th to the 19th centuries.